今天给大家分享的�?014�?月份《Journal of the American Chemical Society》上发表的一篇名为：Hierarchical Hybrid Organic�CInorganic Materials with Tunable Textural Properties Obtained Using Zeolitic-Layered Precursor、�br />
文章摘要如下９�br /> Novel layered zeolitic organic�Cinorganic materials have been synthesized using atwo-dimensional zeolite precursor IPC-1P prepared by a top-down approach from zeolite UTL. The formation of porous materials containing organic linkers or polyhedral oligomeric siloxane covalently bonded to zeolite layers in the interlayer space was confirmed by a variety of characterization techniques (N2/Ar sorption analysis, XRD, 29Si and 13C NMR, TEM). The organic�Cinorganic porous hybrids obtained by intercalation with silsesquioxane posessed layered morphology and contained large crystalline domains. The hybrids exhibited mesoporous or hierarchical micro-/mesoporous systems, stable up to 350 ��C. Textural properties of the formed zeolitic organic�Cinorganic materials can be controlled by varying the linker or synthetic conditions over a broad range. Surface areas and pore volumes of synthesized hybrids significantly exceed those for parent zeolite UTL and corresponding swollen material; the amount of micropores increased with increasing rigidity and size of the organic linker in the order biphenyl > phenylene > ethanediyl.
该文章中材料表征采用的是美国麦克仪器ASAP 2020，使用该仪器获得材料-196��C氮气吸附脱附等温线、�br /> 详情可参考下面链接：
http://pubs.acs.org/doi/abs/10.1021/ja410844f