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Selective degradation of model pollutants in the presence of core@shell TiO2@SiO2 photocatalyst

Selective degradation of model pollutants in the presence of core@shell TiO2@SiO2 photocatalyst

作者:Peter Nadraha, Miran Gaberščekb, Andrijana Sever Škapina

aSlovenian National Building and Civil Engineering Institute, Dimičeva ul. 12, SI-1000 Ljubljana, Slovenia

bNational Institute of Chemistry, Hajdrihova ul. 19, SI-1000 Ljubljana, Slovenia

摘要9/span>Photocatalytic TiO2 degrades organic matter unselectively. However, in certain applications, such as degradation of pollutants, selectivity towards pollutants is beneficial. We synthesized core@shell TiO2@SiO2 nanoparticles with photocatalytic activity featuring a significantly faster preferential degradation of model pollutant (rhodamine B) in presence of abundant concentration of natural organic matter compared to pure TiO2 (P25). The material‘/span>s photocatalytic activity was tested in aqueous medium. The selectivity of prepared effect of core@shell materials is explained based on transmission electron microscopy, nitrogen adsorption, X-ray powder diffraction and zeta potential measurements.


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