15 平/span>
金牌会员
已认?/p>
每周分享：Coke deactivation of Ni and Co catalysts in ethanol steam reforming at mild temperatures in a fluidized bed reactor
今天给大家分享的?014?月份 《International Journal of Hydrogen Energy》上发表的一篇名为：Coke deactivation of Ni and Co catalysts in ethanol steam reforming at mild temperatures in a fluidized bed reactor
文章摘要如下９br /> The deactivation by coke deposition of Ni and Co catalysts in the steam reforming of ethanol has been studied in a fluidized bed reactor under the following conditions: 500 and 700 C; steam/ethanol molar ratio, 6; space time, 0.14 gcatalyst h/gethanol, partial pressure of ethanol in the feed, 0.11 bar, and time on stream up to 20 h. The decrease in activity depends mainly on the nature of the coke deposited on the catalysts, as well as on the physicalCchemical properties (BET surface area, pore volume, metal surface area) of the catalysts. At 500 C (suitable temperature for enhancing the WGS reaction, decreasing energy requirements and avoiding Ni sintering), the main cause of deactivation is the encapsulating coke fraction (monoatomic and polymeric carbon) that blocks metallic sites, whereas the fibrous coke fraction (filamentous carbon) coats catalyst particles and increases their size with time on stream with a low effect on deactivation, especially for catalysts with high surface area. The catalyst with 10 wt% Ni supported on SiO2 strikes a suitable balance between reforming activity and stability, given that both the capability of Ni for dehydrogenation and CCC breakage and the porous structure of SiO2 support enhance the formation of filamentous coke with low deactivation. This catalyst is suitable for use at 500 C in a fluidized bed, in which the collision among particles causes the removal of the external filamentous coke, thus minimizing the pore blockage of the SiO2. At 700 C, the coke content in the catalyst is low, with the coke being of filamentous nature and with a highly graphitic structure.
该文章中材料表征采用的是美国麦克仪器AutoChem 2920
详情可参考下面链接：
http://www.sciencedirect.com/science/article/pii/S0360319914017728
文章摘要如下９br /> The deactivation by coke deposition of Ni and Co catalysts in the steam reforming of ethanol has been studied in a fluidized bed reactor under the following conditions: 500 and 700 C; steam/ethanol molar ratio, 6; space time, 0.14 gcatalyst h/gethanol, partial pressure of ethanol in the feed, 0.11 bar, and time on stream up to 20 h. The decrease in activity depends mainly on the nature of the coke deposited on the catalysts, as well as on the physicalCchemical properties (BET surface area, pore volume, metal surface area) of the catalysts. At 500 C (suitable temperature for enhancing the WGS reaction, decreasing energy requirements and avoiding Ni sintering), the main cause of deactivation is the encapsulating coke fraction (monoatomic and polymeric carbon) that blocks metallic sites, whereas the fibrous coke fraction (filamentous carbon) coats catalyst particles and increases their size with time on stream with a low effect on deactivation, especially for catalysts with high surface area. The catalyst with 10 wt% Ni supported on SiO2 strikes a suitable balance between reforming activity and stability, given that both the capability of Ni for dehydrogenation and CCC breakage and the porous structure of SiO2 support enhance the formation of filamentous coke with low deactivation. This catalyst is suitable for use at 500 C in a fluidized bed, in which the collision among particles causes the removal of the external filamentous coke, thus minimizing the pore blockage of the SiO2. At 700 C, the coke content in the catalyst is low, with the coke being of filamentous nature and with a highly graphitic structure.
该文章中材料表征采用的是美国麦克仪器AutoChem 2920
详情可参考下面链接：
http://www.sciencedirect.com/science/article/pii/S0360319914017728
美国麦克仪器 2014-08-05 | 阅读?342
上一篆/div>
每周分享：The effect of preparation method of the Cu–La2O3–ZrO2/γ-Al2O3 hybrid catalysts on one-step synthesis of dimethyl ether from syngas
